Uniaxial magnetic anisotropy of square-planar chromium(ii) complexes revealed by magnetic and HF-EPR studies

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Uniaxial magnetic anisotropy of square-planar chromium(II) complexes revealed by magnetic and HF-EPR studies.

Two mononuclear square-planar Cr(II) complexes are reported, exhibiting field-induced slow magnetic relaxation. The axial zero-field splitting parameter was unambiguously determined by both a high-frequency/field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements. This result represents the first observed single-molecule-magnet behavior in the square planar coordinatio...

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ژورنال

عنوان ژورنال: Chemical Communications

سال: 2015

ISSN: 1359-7345,1364-548X

DOI: 10.1039/c5cc07025b